000			03298cam a22003737a 4500
001			17206105
005			20240818092947.0
008			120312t2012 gw a frb 001 0 eng
010			_a2012360631
020			_a9783527327171 (pbk.)
020			_a3527327177 (pbk.)
020			_a9783527327164
040			_aUKM _cSTF _dCDX _dYDXCP _dBDX _dMUU _dSFU _dLMR _dKMS _dDLC _dBU-ScBUE
041	1		_aeng _hger
082	0	0	_a547.05045 _222 _bSTE
100	1		_aSteinborn, Dirk _936214
245	1	0	_aFundamentals of organometallic catalysis / _cDirk Steinborn ; [translator Alan Frenkel]
260			_aWeinheim, Germany : _bWiley-VCH Verlag Gmbh & Co. KGaA, _cc.2012 _e([Berlin] : _fAcid-Free Paper)
300			_axvii, 456 p. : _bill. ; _c24 cm.
500			_aIndex : p. 439-455.
504			_aBibliography : p. 407-437.
505	0		_aPrinciples of organometallic catalysis-Elementary steps in organometallic catalysis-Hydrogenation of olefins-Hydroformylation of olefins and Fischer-Tropsch synthesis-Carbonylation of methanol and water-gas shift reaction-Metathesis-Oligomerization olefins-Polymerization of olefins-C-C linkage of dienes-C-C coupling reactions-Hydrocyanation, hydrosilylation, and hydroamination of olefins-Oxidation of olefins and alkanes-Nitrogen fixation.
520			_aCatalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of every-day polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. FInally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis--homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis.
546			_aTranslated from the German.
650		0	_aCatalysis _vTextbooks _936215
650		0	_aOrganometallic chemistry _vTextbooks _936216
653			_bENGGEN _cOctober2014
655			_vreading book _934232
700	1		_aFrenkel, Alan _etranslator. _936217
942			_2ddc _k547.05045 STE _hRDA-MOD
999			_c18455 _d18427
336			_2rdacontent _atext _btxt
337			_aunmediated _2rdamedia _bn
338			_avolume _bnc _2rdacarrier